Š

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ŠIMEK , Michal

Last name: ŠIMEK

First name: Michal

May 24, 2018 (v1)

Publication

Metadata-only

Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters

Carmona, José A. Gonzalo Calvo, Gonzalo de Serrano Vallez, Inmaculada

A series of peracylated glycosamine-derived thioureas have been synthesized and their behavior as bifunctional organocatalysts has been tested in the enantioselective nucleophilic addition of formaldehyde tert-butyl hydrazone to aliphatic α-keto esters for the synthesis of tertiary azomethyl alcohols. Using the...

Uploaded on: December 4, 2022