Preparation of nanocrystalline ZrB2-based powder by aluminothermic and magnesiothermic reductions in M/ZrO2/B 2O3 (M = Al or Mg) systems was investigated. In this research, high energy ball milling was employed to persuade necessary conditions for the occurrence of a mechanically induced self-sustaining reaction (MSR). The course of MSR...
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April 24, 2018 (v1)PublicationUploaded on: December 4, 2022
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April 24, 2018 (v1)Publication
Nanocrystalline zirconium diboride (ZrB2) powder was produced by mechanochemistry from the magnesiothermic reduction in the Mg/ZrO 2/B2O3 system. The use of high-energy milling conditions was essential to induce a mechanically induced self-sustaining reaction (MSR) and significantly reduce the milling time required for complete conversion....
Uploaded on: March 27, 2023 -
April 19, 2018 (v1)Publication
ZrB2-Al2O3 nanocomposite powder was produced by aluminothermic reduction in Al/ZrO2/B2O 3 system. In this research, high energy ball milling was used to produce the necessary conditions to induce a mechanically induced self-sustaining reaction. The ignition time of the composite formation was found to be about 13 min. The synthesis mechanism in...
Uploaded on: March 27, 2023 -
April 24, 2018 (v1)PublicationMechanochemical synthesis of ZrB2-SiC-ZrC nanocomposite powder by metallothermic reduction of zircon
Aluminium and magnesium were used in the M/ZrSiO4/B 2O3/C (M = Al, Mg) system to induce a mechanically induced self-sustaining reaction (MSR). Aluminium was not able to reduce the system to the desired products, and the system became amorphous after 10 h milling. However, nanocomposite powder of ZrB2-SiC-ZrC was in situ synthesized by the...
Uploaded on: December 2, 2022 -
April 13, 2018 (v1)Publication
A ZrSiO4/B2O3/Mg/C system was used to synthesize a ZrB2-based composite through a high-energy ball milling process. As a result of the milling process, a mechanically induced self-sustaining reaction (MSR) was achieved in this system. A composite powder of ZrB2–SiC–ZrC was prepared in situ by a magnesiothermic reduction with an ignition time of...
Uploaded on: March 27, 2023 -
April 19, 2018 (v1)Publication
Herein, ZrSiO4/B2O3/Mg/C system was used to synthesize a ZrB2-based composite by means of a high energy ball milling process. A mechanically induced selfsustaining reaction was achieved in this system. A nanocomposite powder of ZrB2– SiC–ZrC was prepared with an ignition time of approximately 6 minutes of milling. The role of the stoichiometric...
Uploaded on: March 27, 2023