Several activity tests on a zeolite-based catalyst for the ethanol to ethylene dehydration reaction are used to outline the stoichiometry of 4 reactions describing the observed outcome. The heat and mass balances of a reactor were calculated. The thermal input was mainly sustained with a standard product-to-feed heat exchange. Upstream, two...
-
2018 (v1)PublicationUploaded on: April 14, 2023
-
2019 (v1)Publication
A bioethanol reforming system, capable of converting a diluted water-ethanol mixture into hydrogen, is sized and set up to produce 5 kW of electric power via a polymer electrolyte membrane fuel cells (PEMFC). A part of the produced hydrogen supplies heat for the reforming reaction without impairing the power generation, then no additional fuel...
Uploaded on: March 27, 2023 -
2018 (v1)Publication
Second generation bioethanol, obtained by the fermentation of lignocellulosic biomass, which is not competitive with the food and feed field, is one of the most interesting promising biofuels, already available in semi-commercial amount. Steam reforming of bioethanol has been used here for sustainable hydrogen and syngas production. Differently...
Uploaded on: April 14, 2023 -
2018 (v1)Publication
Second generation bioethanol, obtained by the fermentation of lignocellulosic biomass, which is not competitive with the food and feed field, is one of the most interesting promising biofuels, already available in semi-commercial amount. Steam reforming of bioethanol has been used here for sustainable hydrogen and syngas production. Differently...
Uploaded on: October 11, 2023 -
2018 (v1)Publication
The experimental results of testing with different irradiation power are compared and used as a basis for the feasibility assessment and conceptual design of a photoreforming reactor. The highest H2 productivity (0.276 mol H2/h kgcat) was achieved with 1 g/L of 1 wt% Au/TiO2 P25 catalyst by using a 113 W/m2 UVA irradiation. Insufficient...
Uploaded on: April 14, 2023 -
2018 (v1)Publication
The photoreduction of CO2 is an intriguing process which allows the synthesis of fuels and chemicals. One of the limitations for CO2 photoreduction in the liquid phase is its low solubility in water. This point has been here addressed by designing a fully innovative pressurized photoreactor, allowing operation up to 20 bar and applied to...
Uploaded on: April 14, 2023 -
2018 (v1)Publication
Co/SiO2 catalysts with two Co contents of 10 and 30 mol% were prepared and used in ethanol steam reforming. With the aim of tailoring the materials features by varying the synthesis parameters, two different sol–gel procedures were designed, namely a modified hydrolytic alkoxide sol–gel synthesis and a (non-ionic) surfactant assisted one....
Uploaded on: April 14, 2023 -
2019 (v1)Publication
Hydrogen is considered one of the most promising energy vectors in order to match the current energy and environmental issues. Bioethanol steam reforming is a sound opportunity and close to the industrialization considering an integrated biorefinery concept. MgAl 2 O 4 was selected as a stable support, with improved activity, selectivity and...
Uploaded on: April 14, 2023