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BARBARO , P.

Last name: BARBARO

First name: P.

November 24, 2017 (v1)

Publication

Metadata-only

Chiral Rh phosphine–phosphite catalysts immobilized on ionic resins for the enantioselective hydrogenation of olefins in water

Kleman, Patryk Artur Barbaro, P. Pizzano Mancera, Antonio

The asymmetric hydrogenation of prochiral enamides with Rh complexes bearing chiral phosphine–phosphite ligands (P–OP) supported on sulphonated polystyrene resins has been studied. The complexes have been supported by simple treatment of preformed [Rh(diolefin)(P–OP)](BF4) with the Li salt of resins. In MeOH, high enantioselectivities were...

Uploaded on: March 27, 2023