The dynamics of the freezing transition of the rotator phase crystal of ethanol into its orientational glass phase is monitored by measurements of molecular rotational components in the quasielastic neutron scattering spectrum. We demonstrate that phenomena observed at pico- and nanosecond scales can be mapped onto those shown by a model of...
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July 24, 2017 (v1)PublicationUploaded on: March 27, 2023
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May 8, 2017 (v1)Publication
The reorientational dynamics within the rotationally disordered cubic plastic phase of solid ethanol is investigated by means of the concurrent use of computer molecular dynamics and quasielastic neutron scattering. Motions involving widely different time scales are shown to take place above the calorimetric "glass transition" which is centered...
Uploaded on: December 4, 2022 -
May 8, 2017 (v1)Publication
We report measurements of the temperature dependence of the sound attenuation and the fractional change in sound velocity for the glass (G) and orientational-glass (OG) phases of polymorphic ethanol. Strikingly similar behaviors are found for both phases despite the OG's underlying crystal (bcc) lattice. Such similarity, which is also revealed...
Uploaded on: March 27, 2023