CAVATTONI T.

Two 20 wt.% Co/SiO2 catalysts have been prepared using silica gel as a support and cobalt acetate or nitrate as precursors. They were characterized before and after reaction using XRD, skeletal IR and DR-UV–vis-NIR spectroscopies and FE-SEM microscopy. Fresh catalysts are active in CO2 methanation at atmospheric pressure but rapidly deactivate...

Two 20 wt.% Co/SiO2 catalysts were prepared using silica gel as a support and cobalt acetate and nitrate as precursors, respectively. As a comparison unsupported amorphous cobalt nanoparticles (10–80 nm) were synthesized by decomposing cobalt carbonyl. They were characterized before and after reaction using XRD, IR spectroscopy in the range of...

Three Ni-based natural gas steam reforming catalysts, i.e., commercial JM25-4Q and JM57-4Q, and a laboratory-made catalyst (26% Ni on a 5% SiO2-95% Al2O3), are tested in a laboratory reactor, under carbon dioxide methanation and methane steam reforming operating conditions. The laboratory catalyst is more active in both CO2 methanation...

To support the interpretation of the experimental results obtained from two laboratory-scale reactors, one working in the steam methane reforming (SMR) mode, and the other in the CO2 hydrogenation (MCO2) mode, a steady-state pseudo-homogeneous 1D non-isothermal packed-bed reactor model is developed, embedding the classical Xu and Froment local...

No description

Ni-based catalysts, 13.5 Ni wt.%, with enhanced thermal stability and catalytic performance for CO2 methanation have been synthesized with different La2O3 loadings. Catalysts have been extensively characterised by: XRD, IR, H2-TPR, IPA-TPD, UV–vis-NIR, FE-SEM and tested in CO2 methanation. SiO2 addition to Al2O3 support decreases the activity...