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CRISTÓBAL GASGA , Crispín Silvano

Last name: CRISTÓBAL GASGA

First name: Crispín Silvano

October 1, 2018 (v1)

Publication

Metadata-only

Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2

Cristóbal Gasga, Crispín Silvano Álvarez González, Eleuterio Paneque Sosa, Margarita

The Ir(III) pyridylidene TpMe2tiebar above startr(CH2CH2-o-tiebar above endC6H4)(tiebar above startCN(H)CHCHCHtiebar above endCH) (3; TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) reacts with oxygen (air), under mild conditions, to afford a bicyclic ether-semiaminal species. The new structure derives formally from two oxidative events. One is...

Uploaded on: December 4, 2022