CRISTIANI C.

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This study has the main purpose of testing natural carriers as more sustainable alternatives to polymeric coating. New clay‐based hybrid organic–inorganic materials have been prepared. An innovative procedure for the intercalation of the bioactive molecule is proposed. The synthesis process implies the use of mild operating conditions and does...

In this work, ceramic powder dispersion was achieved by using a glycerol/water solution as dispersion medium and polyvinyl alcohol as binder and rheology modifier. Five different powders were dispersed and they were deposited onto open cell ceramic foams: the bare carrier (i.e. cerium oxide) and four catalytically active powders (i.e. nickel,...

Supplemental dietary amino acids (AAs) need to be provided in a form that prevents their degradation along the gastrointestinal tract to guarantee their high bioavailability and bioactivity. In this study, methionine (Met) protected via organo-clay intercalation (natural carriers) has been developed as a sustainable alternative to polymeric...

This study is a starting point for the development of an efficient method for rare earths (REs) and transition metals (TMs) recovery from waste electrical and electronic equipment (WEEE) via a hydrometallurgical process. The capture and release capability of mineral clays (STx) and activated carbons (AC), pristine and modified (STx-L6 and...

Hybrid materials based on clays and polyamines are supposed to be efficient heavy metals sorbents due to the well-known adsorption behaviour of the clay matrix and to the coordination properties of un-protonated amino groups. For this purpose, a montmorillonite clay was modified with three different aliphatic polyamines: L6 and L10 have a...

Uptake and release capability of a new organoclay material were assessed with the final goal to evaluate its applicability in recovering REs from solutions. Capture and release capability have been tested towards a La ions model solution, and interaction mechanism and reactions, active in both capture and release processes, were related to the...

Metals from electric and electronic waste equipment (WEEE) can be recovered by dissolution with acids followed by liquid–liquid extraction. A possible alternative to liquid–liquid extraction is liquid–solid adsorption, where sorbents efficiency is the key factor for process efficiency. In this respect, aim of this paper is the study of the...

In this work, Ca-montmorillonite (STx), natural and modified (STx-L6) with a linear penta-ethylene-hexamine (L6), were tested as sorbents in a liquid/solid process for La and Cu capture in bionic model solutions. Twelve La/Cu ratios in solution were set and analyzed with the final target of investigating the capture mechanisms when both Cu and...

This work focuses on the investigation of the capability of reduced graphene oxide (rGO) filters to remove metals from various wastewater. The process to produce rGO membranes is reported and discussed, as well as their ability to capture ions in complex solutions, such as tap or industrial wastewater. Multi-ion solutions, containing Cu2+,...