DEMAY , Yves

Drawing instabilities and rupture are a serious limitation in polymer fibre and film processing. Draw resonance and fibre or film rupture depend on the processing conditions, heat transfer and on the rheology of the polymer and some of these defects may also be encountered for Newtonian fluids. This paper reviews the different instabilities...

Drawing instabilities and rupture are a serious limitation in polymer fibre and film processing. Draw resonance and fibre or film rupture depend on the processing conditions, heat transfer and on the rheology of the polymer and some of these defects may also be encountered for Newtonian fluids. This paper reviews the different instabilities...

This paper presents an experimental characterization of the volume defects in polystyrene extrusion. In a first step, these defects are quantified in capillary rheometry. In a second step, a transparent slit die, fed by an extruder, is used to perform birefringence experiments and to visualize stress transients during the instability....

The flow behavior of two molten linear high-density polyethylenes (HDPE) is carefully studied using a single screw extruder equipped with a transparent slit die. Flow curves are drawn for both resins and compared. Slit die experiments are performed using birefringence technique to obtain stress fields, and image analysis is developed to...

The oscillating flow instability of a molten linear high-density polyethylene is carefully studied using a single screw extruder equipped with a transparent slit die. Experiments are performed using laser Doppler velocimetry in order to obtain the local velocities field across the entire die width. At low flow rate, the extrusion is stable and...

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The spurt how behavior of a linear high-density polyethylene was carefully studied in capillary experiments. Depending on the flow conditions, new types of complex transients were observed. The study pointed out a second oscillating area, described by a second hysteresis cycle, close to or inside the classical one. In one case, the second...

The film casting process is widely used to produce polymer film: a molten polymer is extruded through a flat die, then stretched in air and cooled on a chill roll. This study is devoted to the extensional flow between the die and the chill roll. The film shows a lateral neck-in as well as an inhomogeneous decrease of the thickness. An...

Film casting process is widely used to produce polymer film: a molten polymer is extruded through a flat die, then stretched in air and cooled on a chill roll. This study is devoted to the extensional flow between the die and the chill roll. The film shows a lateral neck-in as well as a inhomogenous decrease of the thickness. Thickness as well...

An important problem arising in the cast film process is the socalled neck-in phenomenon, which may induce a drastic film width reduction as well as an inhomogeneous film thickness distribution (with the so called "dog-bone" defect on each side of the film). This neck-in phenomenon is highly influenced by the polymer rheology (increasing...

Film blowing, as other elongational polymer forming processes, may present marked drawing instabilities leading to unacceptable products. But in film blowing, these instabilities are much more complex than for example in fibre spinning: there is no stabilizing effect of the polymer cooling, and the symmetry of the process may be broken, leading...

This paper is devoted to the numerical study of the stability of the plane flow for two immiscible fluids obeying Maxwell constitutive equation in a channel of aspect ratio 8. For fixed viscosity and flow rate ratios, the shape and non-linear behavior of interfacial waves induced by small perturbations of the input flow rate are studied using...

A simplified model of the Leslie–Ericksen theory is used to solve the flow of liquid crystalline polymers, seen as viscous anisotropic fluids, making the assumptions of high viscosities and neglecting the director elasticity in the viscosity terms. The resulting equations, known as Ericksen's ''Transversely Isotropic Fluids'' equations involve...

The interface instability of the coextrusion flow of a polyethylene and a polystyrene is studied both experimentally and theoretically in a slit geometry. For prototype industrial conditions, we have found a stable/unstable transition which bounds the occurrence of stable/unstable sheets at die exit. By investigating a large range of processing...

A new coating process involving a short stretching distance (1 mm) and a high draw ratio (around 200) is considered. The resulting thin molten polymer film (around 10 micrometers) is set down on a solid primary film and then covered by another solid secondary film. In experimental studies, periodical fluctuation in the thickness of the coated...

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The stability of two-layer flow of polyethylene and polystyrene is experimentally studied in different flow geometries and for various flow rate ratios. A first coextrusion device allows to stop the coextrusion flow in a very long slit channel, to cool down the polymer sample and to dismantle the die in order to extract extrudate which is then...

Despite the fast growth of co-extruded film production, little research work has been devoted to this process. Films of LDPE, ULDPE, LDPE/ULDPE and ULDPE/LDPE were produced at various processing conditions. A continuous experimental set up was used to evaluate the in-plane birefringence during bubble formation. The data collected were used to...

The interface instability of the coextrusion flow of a polyethylene and a polystyrene is experimentally studied with industrial and laboratory equipments for various flow rates and temperature. Stable and unstable coextrusion conditions are identified as a function of flow rate ratio, shear rate and temperature. It is found that temperature and...

The polymer cast film process consists of stretching a molten polymer film between a flat die and a drawing roll. Drawing instabilities are often encountered and represent a drastic limitation to the process. Newtonian fluid film stretching stability is investigated using two numerical strategies. The first one is a 'tracking' method, which...

Health regulations are becoming increasingly restrictive which leads to develop solvent free laminating processes. Hot melt adhesives represent an interesting solution to bond two pre-printed substrates of polymer for packaging applications for example, but their high viscosities require extruding the polymer formulation through important die...

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The knife-over-roll coating process of plastisol formulations for flooring applications has been investigated. The coexistence of smooth spherical PVC particles and rough calcium carbonate aggregates in a Newtonian plasticizer makes this suspension a more complex system than those encountered in the literature. The shear viscosity has been...

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A plastisol is a suspension of PVC particles and mineral fillers in a liquid phase composed of plasticizer and adjuvants. Plastisol formulations are commonly used in coating processes for flooring application. In the knife-overroll process, they are subjected to a wide range of shear rates (0–105 s21). They are adjusted in order to fulfil the...