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FALCETO , Andrés

Last name: FALCETO

First name: Andrés

September 20, 2018 (v1)

Publication

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Electronic and structural effects of low-hapticity coordination of arene rings to transition metals

Falceto, Andrés Carmona Guzmán, Ernesto Álvarez, Santiago

A DFT computational study and a structural analysis of the coordination of arenes to transition metals in low -hapticity (η1 and η2) modes have been developed, including a pseudosymmetry analysis of the molecular orbitals and the introduction of a hapticity map that makes evident the different degrees of intermediate hapticities. Calculations...

Uploaded on: December 4, 2022
September 14, 2017 (v1)

Publication

Metadata-only

Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands

Carrasco, Mario Mendoza, Irene Álvarez González, Eleuterio

To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether adducts of composition [Mo2(Ar′)(I)(O2CR)2(OEt2)] have been prepared and characterized (Ar′=ArXyl2, R=Me; Ar′=ArMes2, R=Me; Ar′=ArXyl2, R=CF3) (Mes=mesityl; Xyl=2,6-Me2C6H3, from now on xylyl) and their reactivity toward...

Uploaded on: March 27, 2023