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FERNÁNDEZ ESPADA-PASTOR , María

Last name: FERNÁNDEZ ESPADA-PASTOR

First name: María

April 15, 2019 (v1)

Publication

Metadata-only

Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5

Moreno Díaz, Juan José Fernández Espada-Pastor, María Campos Manzano, Jesús

C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ligands PMe2ArXyl2 and PMe2ArDipp2. Different pathways are defined for the conversion of the five-coordinate complexes [(η5-C5Me5)IrCl(PMe2Ar')]+, 2(Xyl)+ and 2(Dipp)+, into the corresponding pseudoallyls 3(Xyl)+ and 3(Dipp)+....

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