The interaction of propene with Ag(001) is investigated by high resolution electron energy loss spectroscopy and supersonic molecular beam methods under ultra high vacuum conditions. Propene adsorbs molecularly at 110 K and desorbs intact leaving a clean surface after annealing to 160 K. Two adsorption sites, characterized by slightly different...
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2005 (v1)PublicationUploaded on: April 14, 2023
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2001 (v1)Publication
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Uploaded on: March 27, 2023 -
2005 (v1)Publication
We report on the experimental evidence of the role of rotational alignment of the gas-phase molecules in the interaction of propylene with Ag(001). Molecular alignment has been controlled by a velocity selection of the impinging molecules, flying in a supersonic seeded molecular beam. The experimental findings indicate that at low surface...
Uploaded on: March 27, 2023 -
2004 (v1)Publication
A light and compact mechanical velocity selector, of novel design, for applications in supersonic molecular-beam studies has been developed. It represents a simplified version of the traditional, 50 year old, slotted disks velocity selector. Taking advantage of new materials and improved machining techniques, the new version has been realized...
Uploaded on: April 14, 2023 -
2005 (v1)Publication
The control of spatial orientation of molecules has a great influence on the stereodynamics of elementary processes occurring both in homogeneous and heterogeneous phases. Nonpolar molecules have so far escaped direct experimental investigations because of their poor sensitivity to several external constraints. Recently, it has been shown that...
Uploaded on: March 31, 2023