Halide exchange is a popular strategy to tune the properties of CsPbX3 nanocrystals after synthesis. However, while Cl ? Br and Br ? I exchanges proceed through the formation of stable mixed-halide nanocrystals, the Cl? I exchange is more elusive. Indeed, the large size difference between chloride and iodide ions causes a miscibility gap in the...
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2023 (v1)PublicationUploaded on: October 11, 2024
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2022 (v1)Publication
Simultaneously achieving both broad absorption and sharp emission in the near-infrared (NIR) is challenging. Coupling of an efficient absorber such as lead halide perovskites to lanthanide emissive species is a promising way to meet the demands for visible-to-NIR spectral conversion. However, lead-based perovskite sensitizers suffer from...
Uploaded on: March 27, 2023 -
2024 (v1)Publication
We report a colloidal synthesis of blue emissive, stable cube-shaped CsPbBr3 quantum dots (QDs) in the strong quantum confinement regime via dissolution-recrystallization starting from pre-syntesized (KxCs1-x)4PbBr6 nanocrystals which are then reacted with PbBr2. This is markedly different from the known case of Cs4PbBr6 nanocrystals that react...
Uploaded on: October 11, 2024