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LAGLERA GÁNDARA , Carlos J.

Last name: LAGLERA GÁNDARA

First name: Carlos J.

August 30, 2024 (v1)

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σ‑GeH and Germyl Cationic Pt(II) Complexes

Laglera Gándara, Carlos J. Ríos Moreno, Pablo Fernández de Córdova, Francisco José

The low electron count Pt(II) complexes [Pt(NHC′)(NHC)]- [BArF] (where NHC is a N-heterocyclic carbene ligand and NHC′ its metalated form) react with tertiary hydrogermanes HGeR3 at room temperature to generate the 14-electron platinum(II) germyl derivatives [Pt(GeR3)(NHC)2][BArF]. Low-temperature NMR studies allowed us to detect and...

Uploaded on: August 31, 2024
October 17, 2024 (v1)

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Electrophilic Hydrosilylation of Electron-Rich Alkenes Derived from Enamines

Laglera Gándara, Carlos J. Fernández de Córdova, Francisco José Jiménez Pérez, Julián

The low-electron count, air-stable, platinum complexes [Pt(ItBu')(ItBu)][BArF] (C1) (ItBu=1,3-di-tert-butylimidazol-2-ylidene), [Pt(SiPh)3(ItBuiPr)2][BArF] (C2) (ItBuiPr=1-tert-butyl-3-iso-propylimidazol-2-ylidene), [Pt(SiPh)3(ItBuMe)2][BArF] (C3), [Pt(GePh3)(ItBuiPr)2][BArF] (C4), [Pt(GePh)3(ItBuMe)2][BArF] (C5) and [Pt(GeEt)3(ItBuMe)2][BArF]...

Uploaded on: October 18, 2024