MATAS RUÍZ , Inmaculada

Last name: MATAS RUÍZ

First name: Inmaculada

April 16, 2015 (v1)

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Complejos nucleófilos de níquel (II) que contienen ligandos hidróxido, alcóxido, amiduro y enolato. Síntesis y reactividad

Matas Ruíz, Inmaculada

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Uploaded on: March 27, 2023
October 15, 2018 (v1)

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Migratory insertion reactions of nickel and palladium σ-alkyl complexes with a phosphinito-imine ligand†‡

Ortíz de la Tabla González, Laura Matas Ruíz, Inmaculada Álvarez González, Eleuterio

Ligand exchange reactions have been used for the synthesis of metallacyclic complexes of Ni and Pd of the type [M[upper bond 1 start](CH2CMe2-o-C6[upper bond 1 end]H4)(P–N)], where P–N is the phosphinito-imine ligand P(iPr)2OC(Me)[double bond, length as m-dash]N(2,6-C6H3(iPr)2. The protic acid [H(OEt2)(BAr′4)] (Ar′ = 3,5-C6H3(CF3)2) selectively...

Uploaded on: December 4, 2022
October 11, 2018 (v1)

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Nickel and Palladium Complexes with New Phosphinito-Imine Ligands and Their Application as Ethylene Oligomerization Catalysts

Ortiz de la Tabla González, Laura Matas Ruíz, Inmaculada Palma Ramírez, María del Pilar

Phosphinito-imines, a new class of P,N donors, are readily generated by reaction of bulky arylamide anions [R2CONAr]− (R2 = Me or t-Bu; Ar = 2,6-i-Pr2C6H4) with chlorophosphines ClP(R1)2. In solution, free phosphinito-imines exist in equilibrium with the corresponding amidophosphine tautomers, containing a nitrogen-bound P(R1)2 group. However,...

Uploaded on: March 27, 2023

MATAS RUÍZ , Inmaculada

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