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MENDOZA , Irene

Last name: MENDOZA

First name: Irene

September 20, 2018 (v1)

Publication

Metadata-only

Synthesis and structure of mixed carboxylate-aminopyridinate and -amidinate complexes of dimolybdenum and ditungsten

Mendoza, Irene Curado, Natalia Carrasco Delgado, Mario

We describe in this paper the synthesis and structural characterization of dimolybdenum and ditungsten complexes with MM bonds derived from the metal–metal bonded tetracarboxylates [M2(O2CR)4] and incorporating one or two bulky aminopyridinate or amidinate ligands. The new compounds were isolated in good yields from reactions of the...

Uploaded on: March 27, 2023
September 14, 2017 (v1)

Publication

Metadata-only

Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands

Carrasco, Mario Mendoza, Irene Álvarez González, Eleuterio

To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether adducts of composition [Mo2(Ar′)(I)(O2CR)2(OEt2)] have been prepared and characterized (Ar′=ArXyl2, R=Me; Ar′=ArMes2, R=Me; Ar′=ArXyl2, R=CF3) (Mes=mesityl; Xyl=2,6-Me2C6H3, from now on xylyl) and their reactivity toward...

Uploaded on: March 27, 2023