MICHAŁOWSKI , Tadeusz

The compact thermodynamic approach to the systems containing calcium, magnesium, and carbonate species is referred to dissolution of dolomite, as an example of nonequilibrium ternary salt when introduced into aqueous media. The study of dolomite is based on all attainable physicochemical knowledge, involved in expressions for equilibrium...

The general formulation of dynamic buffer capacity for polyprotic acids and bases (and polyprotic acid and base salts) has been derived. Polyprotic acids show buffer capacity over a broad range of pH values, according to their successive protonation constants. Polyprotic acids with equidistant pki values behave as universal buffers. The paper...

This paper refers to inflection point—the fundamental property of S-shaped curves. In this paper, the inflection points are related to pH titration curve pH = pH(V), and to the curve σ = σ(pH) in-volved with surface tension, σ.