M

J

MORALES CERÓN , Judith

Last name: MORALES CERÓN

First name: Judith

January 27, 2023 (v1)

Publication

Metadata-only

Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts

Morales Cerón, Judith Lara Muñoz, Patricia López Serrano, Joaquín

Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation catalyst precursors. Particularly, when the steric hindrance of the picolyl fragment is increased, a catalyst...

Uploaded on: March 1, 2023
August 10, 2018 (v1)

Publication

Metadata-only

Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds

Hernández Juárez, Martín López Serrano, Joaquín Lara Muñoz, Patricia

A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the corresponding silver‐carbene derivatives. Characterization of these derivatives shows both mer and fac coordination of the CNC ligands depending on the wingtips of the N‐heterocyclic carbene fragments. In the presence of tBuOK,...

Uploaded on: March 24, 2023