In the laboratory, the photo-and thermochemical evolution of ices, made of simple molecules of astrophysical relevance, always leads to the formation of semi-refractory water-soluble organic residues. Targeted searches for specific molecules do reveal the notable presence of two families of important molecular "bricks of life": amino acids, key...
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April 14, 2018 (v1)Conference paperUploaded on: December 4, 2022
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April 14, 2018 (v1)Conference paper
In the laboratory, the photo-and thermochemical evolution of ices, made of simple molecules of astrophysical relevance, always leads to the formation of semi-refractory water-soluble organic residues. Targeted searches for specific molecules do reveal the notable presence of two families of important molecular "bricks of life": amino acids, key...
Uploaded on: February 22, 2023 -
2019 (v1)Journal article
In the laboratory, the photo-and thermochemical evolution of ices, made of simple molecules of astrophysical relevance, always leads to the formation of semi-refractory water-soluble organic residues. Targeted searches for specific molecules do reveal the notable presence of two families of important molecular " bricks of life " , amino acids,...
Uploaded on: December 4, 2022 -
March 14, 2015 (v1)Journal article
All life on Earth is characterized by its asymmetry – both the genetic material and proteins are composed of homochiral monomers. Understanding how this molecular asymmetry initially arose is a key question related to the origins of life. Cometary ice simulations, L-enantiomeric enriched amino acids in meteorites and the detection of circularly...
Uploaded on: March 26, 2023 -
2018 (v1)Journal article
Living organisms on the Earth almost exclusively use l-amino acids for the molecular architecture of proteins. The biological occurrence of d-amino acids is rare, although their functions in various organisms are being gradually understood. A possible explanation for the origin of biomolecular homochirality is the delivery of enantioenriched...
Uploaded on: December 4, 2022 -
January 3, 2014 (v1)Journal article
Circularly polarized light (CPL) is known to be a true chiral entity capable of generating absolute molecular asymmetry. However, the degree of inducible optical activity depends on the λ of the incident CPL. Exposure of amorphous films of rac-alanine to tunable CPL led to enantiomeric excesses (ee) which not only follow the helicity but also...
Uploaded on: March 26, 2023 -
January 26, 2022 (v1)Journal article
Life on Earth employs chiral amino acids in stereochemical L-form, but the cause of molecular symmetry breaking remains unknown. Chiroptical properties of amino acidsexpressed in circular dichroism (CD)have been previously investigated in solid and solution phase. However, both environments distort the intrinsic charge distribution associated...
Uploaded on: December 3, 2022 -
2017 (v1)Journal article
We detected ribose and related sugars in the organic residues of simulated interstellar ices using multidimensional gas chromatography. Kawai questions the formation of sugar compounds in the ices and suggests that they arise from a classical formose reaction during sample workup for analysis. We disagree with this hypothesis and present...
Uploaded on: December 3, 2022 -
April 8, 2016 (v1)Journal article
This folder includes:*Supplementary Material (.pdf)(Materials and Methods, Figs. S1–S6, Table S1, caption for movie S1)Other supplementary materials available for this manuscript: *Movie S1 (.mp4)*GC×GC chromatograms of ice sample and blank recorded with LECO Corp ChromaTOFTM (.peg)
Uploaded on: February 28, 2023 -
February 2011 (v1)Journal article
The delivery of organic matter to the primitive Earth via comets and meteorites has long been hypothesized to be an important source for prebiotic compounds such as amino acids or their chemical precursors that contributed to the development of prebiotic chemistry leading, on Earth, to the emergence of life. Photochemistry of...
Uploaded on: February 28, 2023 -
April 2012 (v1)Journal article
International audience
Uploaded on: February 28, 2023