PASTOR NAVARRO , Antonio

La presente Tesis Doctoral se ha concebido como una continuación natural de trabajos realizados por nuestro grupo de Investigación y pretende efectuar una nueva contribución a la química de los elementos de Mo y W en las dos áreas antes citadas. En el primer c ... apítulo se estudian diversos complejos de estos elementos con ligados de tipo...

Imido ligands have been widely used as stabilizing ligands in highoxidationstate transition metal complexes. Their chemistry has experienced a remarkable growth due to the role they play in many important reactions. Following our interest in this area, we have extended our recent results in the synthesis of bis(imido) complexes of molybdenum,...

The zinc thiodipropionate complex [Zn(tdp)] (1) [tdp = S(CH 2CH2COO)22-] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na2CO 3 and thiodipropionic acid. The bonding preferences of the tdp anion were studied by DFT methods. The reaction of 1 with o-phenanthroline (phen) gave the dinuclear compound...