ROALES , Javier

Tetracationic porphyrin (TMPyP) molecules were incorporated into an optically transparent TiO2 thin film, prepared by Glancing Angle Physical Vapour Deposition (GAPVD), by simple infiltration (at pH 6.4). The preparation of optically transparent TMPyP/TiO2 composite thin films provides a method for the integration of the porphyrin molecules...

Tree diversity can promote both predator abundance and diversity. However, whether this translates into increased predation and top-down control of herbivores across predator taxonomic groups and contrasting environmental conditions remains unresolved. We used a global network of tree diversity experiments (TreeDivNet) spread across three...

The anchoring effect on free-base carboxyphenyl porphyrin films using TiO2 microstructured columns as a host matrix and its influence on NO2 sensing have been studied in this work. Three porphyrins have been used: 5-(4-carboxyphenyl)10,15,20- triphenyl-21H,23H-porphyrin (MCTPP); 5,10,15,20-tetrakis(4-carboxyphenyl)-21H,23Hporphyrin (p-TCPP);...

Open porous and transparent microcolumnar structures of TiO2 prepared by physical vapour deposition in glancing angle configuration (GLAD-PVD) have been used as host matrices for two different fluorescent cationic porphyrins, 5-(N-methyl 4-pyridyl)-10,15,20-triphenyl porphine chloride (MMPyP) and meso-tetra (N-methyl 4-pyridyl) porphine...

The optical gas sensing properties of Zn-(ii)-5,10,15,20-tetra(3- carboxyphenyl)porphyrin (m-ZnTCPP) and Zn-(ii)-5,10,15,20-tetra(4-carboxyphenyl) porphyrin (p-ZnTCPP) bound to microcolumnar TiO2 thin films have been compared and explained in terms of their different molecular structure and anchoring to the titania surface. This different...