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RODRIGUEZ , José A.

Last name: RODRIGUEZ

First name: José A.

June 3, 2022 (v1)

Publication

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Cu Deposited on CeOx-Modified TiO2(110): Synergistic Effects at the Metal-Oxide Interface and the Mechanism of the WGS Reaction

Plata Ramos, José Javier Graciani Alonso, Jesús Evans, Jaime

Experimental techniques and DFT calculations have been combined to study and compare the effect of the metal-substrate interaction in Cu/TiO2(110) and Cu/CeOx/TiO2(110) catalysts for the water-gas shift (WGS) reaction. Experiments and theory show that CeOx nanoparticles affect the dispersion of copper on titania, and on the formed copper-ceria...

Uploaded on: December 4, 2022
May 31, 2022 (v1)

Publication

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Water-Gas Shift Reaction on K/Cu(111) and Cu/K/TiO2(110) Surfaces: Alkali Promotion of Water Dissociation and Production of H2

Rodriguez, José A. Rodríguez Remesal, Elena Ramírez, Pedro J.

The addition of potassium atoms to Cu(111) and Cu/TiO2(110) surfaces substantially enhances the rate for water dissociation and the production of hydrogen through the water-gas shift reaction (WGS, CO + H2O → H2 + CO2). In the range of temperatures investigated, 550-625 K, Cu/K/TiO2(110) exhibits a WGS activity substantially higher than those...

Uploaded on: December 4, 2022