Los resultados experimentales correspondientes a procesos de transferencia electrónica en disolventes mixtos (agua/co-disolvente orgánico) revelan un comprotamiento anormal, en el sentido de que la energía de reorganización del disolvente varía en forma opuesta a la que señalan las teorias al uso. Con objeto de acalarar esta custión se...
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December 28, 2020 (v1)PublicationUploaded on: March 27, 2023
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April 29, 2020 (v1)Publication
The structure of mixtures of dipolar hard sphere fluids with components of equal size but different dipole moments around a single ion is studied. The solvation energy and the polarization around the ion is obtained in the framework of the mean spherical approximation (MSA). Our theoretical results and the results of other workers are compared...
Uploaded on: March 27, 2023 -
April 29, 2020 (v1)Publication
We study the behavior of the reorganization energy for simple charge transfer reactions in mixtures of dipolar hard sphere fluids by Monte Carlo simulation. The static dielectric constants of the solvents are also obtained from the simulation. They are used as input in the reorganization energy expressions provided by the Marcus theory and the...
Uploaded on: March 27, 2023