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SÁNZ GARRIDO , Jorge

Last name: SÁNZ GARRIDO

First name: Jorge

November 14, 2022 (v1)

Publication

Metadata-only

Synthesis and characterization of chiral bidentate bis(N-heterocyclic carbene)-carboxylate palladium and nickel complexes

Sánchez, Adrián Sánz Garrido, Jorge Carrasco Carrasco, Carlos Jesús

Complexes [Pd{(S)-NHCMes,R}2] (R = Me, 2a; iPr, 2b; iBu, 2c) and [Pd{(R)-NHCMes,Me}2] (2a') were prepared by reaction of the corresponding imidazolium precursor [ImMes,R] (namely (S)–2-alkyl(3-mesityl-1H-imidazol-3- ium-1-yl)acetate, 1a-c, and (R)-2-methyl(3-mesityl-1H-imidazol-3-ium-1-yl)acetate, 1a'), with Ag2O and sub- sequent interaction...

Uploaded on: March 24, 2023