V. SANCHEZ ESCRIBANO

The interaction of methane, ethane and ethylene, and of some C1 and C2 oxygenates on the surface of model oxidation catalysts (Co3O4 and Pd-TiO2) has been investigated by FT-IR spectroscopy. Oxidation of alkanes is observed on Co3O4 starting from near 673 K, and near 373 K on Pd-TiO2. Olefins are oxidized already at room temperatures. Attempts...

The adsorption, desorption and catalytic oxidation of 2-propanol has been investigated over a vanadia-titania catalyst without and with potassium doping. 70 % yields in acetone can be obtained at 443 K over vanadia-titania, with propylene and carbon oxides as the main by-products. Potassium doping causes a slight reduction in activity but a...

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