Green material composites from renewable resources: Polymorphic transitions and phase diagram of beeswax/rosin resin
- Others:
- Centre de Mise en Forme des Matériaux (CEMEF) ; Mines Paris - PSL (École nationale supérieure des mines de Paris) ; Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)
- Laboratoire Chimie des Matériaux Organiques et Métalliques (CMOM) ; Université Nice Sophia Antipolis (1965 - 2019) (UNS) ; COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)
Description
Rosin and beeswax are two complex natural materials presenting numerous applications in paints, adhesives, varnishes or inks. Melted, they are particularly interesting for their adhesion properties. This paper establishes the first phase diagram beeswax/rosin blends. A systematic approach using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and polarised optical microscopy (POM) has been performed in order to describe the crystallographic structure and the thermal properties of two materials, beeswax and rosin, and their blends. Indeed, melting, softening and crystallisation temperatures, polymorphic transitions but also crystalline index has been investigated. The resulting phase diagram reveals a complex behaviour in terms of phase transformation and time-dependent phenomenon mainly representative of the complex composition of beeswax.
Abstract
International audience
Additional details
- URL
- https://hal-mines-paristech.archives-ouvertes.fr/hal-00598744
- URN
- urn:oai:HAL:hal-00598744v1
- Origin repository
- UNICA