Published February 19, 2018 | Version v1
Publication

Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

Description

The preparation of new Ru(ii) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.

Abstract

Ministerio de Economía y Competitividad CTQ2009-11867, CSD2007-00006

Abstract

Junta de Andalucía 2008/FQM-3830, 2009/FQM-4832

Additional details

Created:
December 2, 2022
Modified:
November 29, 2023