Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines

Description

Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular functionalization of a C-H bond of the terphenyl group mediated by the Pd(ii) center.

Abstract

Ministerio de Ciencia, Innovación y Universidades CTQ2017-82893-C2-2-R

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