A general algebraic model for molecular vibrational spectroscopy

Description

We introduce the anharmonic oscillator symmetry model to describe vibrational excitations in molecular systems exhibiting a high degree of symmetry. A systematic procedure is proposed to establish the relation between the algebraic and configuration space formulations, leading to new interactions in the algebraic model. This approach incorporates the full power of group theoretical techniques and provides reliable spectroscopic predictions. We illustrate the method for the case of script D3h-triatomic molecules.

Abstract

European Community CI1*-CT94-0072

Abstract

DGAPA-UNAM IN105194

Abstract

CONACyT-Mexico 400340-5-3401E

Abstract

Dirección General de Investigación Científica y Técnica PB92-0663

Additional details