Published November 23, 2017 | Version v1
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A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles

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Description

The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation.

Abstract

Junta de Andalucía CTQ2012-30962, FQM6276

Abstract

European Union NANOSONWINGS 2009-246763

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URL
https://idus.us.es/handle/11441/66567
URN
urn:oai:idus.us.es:11441/66567

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