Impact of particle stiffness on shear-thinning of non-Brownian suspensions

Description

We attempt to identify the impact of particle stiffness on the shear-thinning behavior exhibited by frictional and adhesive non-Brownian suspensions. To this aim, we compare the rheological behavior of three suspensions whose particles have different Young's moduli. The stiffest particles are Soda-lime glass beads with a Young modulus of 70 GPa. The two other kinds of particles are made of polydimethylsiloxane and have been manufactured using a homemade millifluidic device that allowed us to produce batches of sparsely polydisperse particles with tunable Young modulus: 1.8 MPa for the softest ones and 15 MPa for the stiffest. We show that the observed shear-thinning is mainly caused by the presence of adhesive forces between particles. For each of the three suspensions, the shear-thinning behavior is described by the variation of the jamming volume fraction, φ m , with stress, σ , and the results are interpreted in the light of the model proposed by [Richards et al., J. Rheol. 64(2), 405-412 (2020)]. We show that the magnitude of variation of φ m with σ is greater the lower the particle stiffness. More precisely, in the adhesive regime, decreasing the particle stiffness leads to a significant decrease in the value of the jamming fraction while, as predicted by the JKR theory, the characteristic adhesion stress, σ a , does not vary with stiffness. We finally show that, for stresses much higher than σ a , the suspensions behave like usual frictional suspensions with a viscosity controlled by both the particle volume fraction and the value of the interparticle friction coefficient.

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