Electrical Performance of Orthotropic and Isotropic 3YTZP Composites with Graphene Fillers

Description

3 mol% yttria tetragonal zirconia polycrystal (3YTZP) composites with orthotropic or isotropic microstructures were obtained incorporating few layer graphene (FLG) or exfoliated graphene nanoplatelets (e-GNP) as fillers. Electrical conductivity was studied in a wide range of contents in two configurations: perpendicular (σꓕ) and parallel (σ//) to the pressing axis during spark plasma sintering (SPS). Isotropic e-GNP composites presented excellent electrical conductivity for high e-GNP contents (σꓕ ∼ 3200 S/m and σ// ∼ 1900 S/m for 20 vol% e-GNP), consequence of their misoriented distribution throughout the matrix. Optimum electrical performance was achieved in the highly anisotropic FLG composites, with high electrical conductivity for low contents (σꓕ ∼ 680 S/m for 5 vol%), percolation threshold below 2.5 vol% FLG and outstanding electrical conductivity for high contents (σꓕ ∼ 4000 S/m for 20 vol%), result of the high aspect ratio and low thickness of FLG.

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Ministerio de Ciencia e Innovación GC2018–101377-B-100, MCIN/AEI/ 10.13039/501100011033

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European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) P20_01024

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Ministerio de Economía y Competitividad BES-2016- 078711

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Universidad de Sevilla USE-18740-H

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