Advanced characterization and optical simulation for the design of solar selective coatings based on carbon: transition metal carbide nanocomposites

Description

Solar selective coatings based on carbon transition metal carbide nanocomposite absorber layers were designed. Pulsed filtered cathodic arc was used for depositing amorphous carbon:metal carbide (a-C:MeC, Me ¼ V, Mo) thin films. Composition and structure of the samples were characterized by ion beam analysis, X-ray diffraction, Raman spectroscopy, and transmission electron microscopy. The optical properties were determined by ellipsometry and spectrophotometry. Three effective medium approximations (EMA), namely Maxwell-Garnett, Bruggeman, and Bergman, were applied to simulate the optical behaviour of the nanocomposite thin films. Excellent agreement was achieved between simulated and measured reflectance spectra in the entire wavelength range by using the Bergman approach, where in-depth knowledge of the nanocomposite thin film microstructure is included. The reflectance is shown to be a function of the metal carbide volume fraction and its degree of percolation, but not dependent on whether the nanocomposite microstructure is homogeneous or a self-organized multilayer. Solar selective coatings based on an optimized a-C:MeC absorber layer were designed exhibiting a maximum solar absorptance of 96% and a low thermal emittance of 5% and 15% at 25 and 600 °C, respectively. The results of this study can be considered as a predictive design tool for nanomaterial-based optical coatings in general.

Abstract

H2020 RISE project "Framework of Innovation for Engineering of New Durable Solar Surfaces FRIENDS2, GA-645725

Abstract

Centro para el Desarrollo Tecnológico Industrial IDI-20130896 (INDESOL)

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