Published March 6, 2023 | Version v1
Publication

Zero-valent ML2complexes of Group 10 Metals Supported by Terphenyl Phosphanes

Description

Bulky terphenyl phosphane ligands PMe2Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni-Careneinteractions with the terphenyl fragment.

Abstract

Ministerio de Ciencia, Innovación y Universidades CTQ2014-52769-C3-3-R, CTQ2017-82893-C2-2-R

Abstract

Universidad de Sevilla US1262266

Additional details

Created:
March 25, 2023
Modified:
December 1, 2023