Published January 3, 2018
| Version v1
Publication
Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes
Description
1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allow direct observation of alkyl iron intermediates as well as reversible ethylene coordination to the metal center, providing for the first time experimental evidence for a coordination-insertion mechanism of iron-catalysed ethylene upgrade reactions.
Abstract
Ministerio de Economía y Competitividad CTQ2012-30962
Abstract
Junta de Andalucía FQM5074
Additional details
- URL
- https://idus.us.es/handle/11441/68196
- URN
- urn:oai:idus.us.es:11441/68196
- Origin repository
- USE