Mechanical Behaviour and Induced Microstructural Development upon Simultaneous and Balanced Biaxial Stretching of Poly(ethylene furandicarboxylate), PEF

The biaxial behavior of PEF has been analyzed for equilibrated and simultaneous biaxial stretching. The ability of PEF to develop an organized microstructure through strain induced crystallization (SIC) has been described. Upon biaxial stretching, SIC can be difficult to perform because the stretching is performed in two perpendicular directions. However, thanks to the time/temperature superposition principle and an accurate heating protocol, relevant stretching settings have been chosen to stretch the material in its rubbery-like state and to reach high levels of deformation. By the protocol applied, the mechanical behavior is easily transposable to the industry. This work has shown that PEF can, as in uniaxial stretching, develop well-organized crystals and a defined microstructure upon biaxial stretching. This microstructure allows the obtention of improved mechanical properties and thermal stability of the biaxially stretched samples. The crystals induced upon biaxial stretching are similar to the one that has been developed and observed after uniaxial stretching and upon static crystallization. Moreover, the furan cycles seem to appear in a state similar to the one of a sample crystallized upon quiescent condition. The rigidity is increased, and the α-relaxation temperature is increased by 15 °C.