ESQUIVIAS FEDRIANI , Luis María

Este trabajo viene a completar el estudio estructural de la región de formación de amorfos del sistema Al-As-Te, del que se ha podido observar experimentalmente que presenta el efecto conmutación y exhibe características de cristalización notablemente diferentes en función de la composición. Después de una síntesis de los conocimientos que...

Supercritically dried composites have already been analysed and proposed as carbon dioxide sequesters. However, the economical and energetic costs of the supercritical drying process had to be re-evaluated, and were eventually found not to enhance the feasibility of the proposed route for CO2 mineral sequestration. Different composites series...

The aim of this study was to investigate the adsorption of basic yellow, a cationic dye, from aqueous solution by natural stevensite, with 104m2/g of specific surface area. The kinetics and the effects of several experimental parameters such as the pH of the solution, adsorbent dose and initial dye concentration were researched using a batch...

Processes of carbonation of calcium-rich aqueous industrial wastes from acetylene production were performed mimicking rock weathering, using the atmospheric carbon dioxide as reactant. This residue was carbonated exposing it to the air in artificial pools with controlled solid-to-liquid and surface-to-volume ratios, and the efficiency of this...

La producción industrial del ácido fosfórico presenta una gran demanda debido al uso cada vez mayor de fertilizantes, detergentes o productos de limpieza. Este proceso genera cada año millones de toneladas de fosfoyesos como residuo. La posibilidad de incorporación de este residuo en el desarrollo de morteros tiene como objetivo principal...

In this work, the crystal evolution of α-Al2O3 composites reinforced with LBA platelets were monitored by XRD Rietveld. In addition, the mechanical properties of totally densified specimens were researched by Vickers and Knoop indentations. These composite materials were prepared by a sol-gel process from alumina seeded boehmite sol and...

La presente invención se refiere a un uso de una suspensión acuosa que comprende calcio en una proporción mayor al 15% en peso, siendo la fase sólida de la suspensión acuosa preferiblemente portlandita procedente de residuos de la industria química, para

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The weathering reactions of hydration and carbonation of nanostructured calcium oxide with atmospheric moisture and carbon dioxide have been characterized. This work is the first-to-date combined kinetic and nanostructural research on CaO oriented to two key processes for different systems, i.e. hardening of construction materials and carbon...

This work explored several synthesis routes to obtain calcium silicates from different calcium-rich and silica-rich industrial residues. Larnite, wollastonite and calcium silicate chloride were successfully synthesised with moderate heat treatments below standard temperatures. These procedures help to not only conserve natural resources, but...

Procedimiento de captura de CO2 y SO2.La presente invención se refiere a un procedimiento de captura de CO2 y SO2 que comprende a) introducir una corriente acuosa de un hidróxido de un metal alcalino o alcalinotérreo y otra gaseosa de CO2 en un depurador-

Se han obtenido aerogeles híbridos de sílice orgánico-inorgánico por aplicación de ultrasonidos de alta potencia en los precursores líquidos y posterior secado del gel húmedo en condiciones supercríticas en etanol. Las cadenas orgánicas no se degradan térmicamente y aceleran el proceso de contracción de la red por activación térmica. Los...

Acoustic cavitation effects in sol-gel liquid processing permits to obtain nanostructured materials, with size-dependent properties. The so-called "hot spots" produce very high temperatures and pressures which act as nanoreactors. Ultrasounds force the dissolution and the reaction stars. The products (alcohol, water and silanol) help to...

Adsorption of flue gases by single-wall carbon nanotubes (SWCNT) has been studied by means of Monte Carlo simulations. The flue gas is modeled as a ternary mixture of N2, CO2, and O2, emulating realistic compositions of the emissions from power plants. The adsorbed flue gas is in equilibrium with a bulk gas characterized by temperature T ,...

A two-fold objective is proposed for this research: removing hazardous and unpleasant wastes and mitigating the emissions of green house gasses in the atmosphere. Thus, the first aim of this work is to identify, characterize and recycle industrial wastes with high contents of calcium or sodium. This involves synthesizing materials with the...

A new structural model based on the premises widely used for describing the structure of aerogels has been introduced. These structures have been described as an assemblage of randomly-packed spheres in several hierarchically-ordered levels. A new algorithm has been developed for constructing our models from these premises using computer...

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This paper presents the results of the carbonation reaction of two sample types: larnite (Ca2SiO4) powders and larnite/silica aerogel composites, the larnite acting as an active phase in a process of direct mineral carbonation. First, larnite powders were synthesized by the reaction of colloidal silica and calcium nitrate in the presence of...

Industrial wet phosphoric acid production in Huelva (SW Spain) has led to the controversial stockpiling of waste phosphogypsum by-products, resulting in the release of significant quantities of toxic impurities in salt marshes in the Tinto river estuary. In the framework of the fight against global climate change and the effort to reduce carbon...